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Beilstein J. Org. Chem. 2009, 5, No. 19, doi:10.3762/bjoc.5.19
Graphical Abstract
Scheme 1: Enantioselective addition of trimethylsilyl cyanide to benzaldehyde.
Scheme 2: Asymmetric catalytic hydrogenation in a falling-film microreactor.
Scheme 3: Aldol reaction catalyzed by 5-(pyrrolidine-2-yl)tetrazole.
Scheme 4: Enantioselective addition of diethylzinc to aryl aldehydes.
Scheme 5: Glyoxylate-ene reaction in flow.
Scheme 6: Asymmetric synthesis of ß-lactams.
Scheme 7: α-Chlorination of acid chlorides in flow.
Scheme 8: Asymmetric Michael reaction in continuous flow.
Scheme 9: Enantioselective addition of Et2Zn to benzaldehyde using monolithic chiral amino alcohol.
Scheme 10: Continuous-flow hydrolytic dynamic kinetic resolution of epibromohydrin (32).
Scheme 11: Continuous-flow asymmetric cyclopropanation.
Scheme 12: Continuous asymmetric hydrogenation of dimethyl itaconate in scCO2.
Scheme 13: Continuous asymmetric transfer hydrogenation of acetophenone.
Scheme 14: Asymmetric epoxidation using a continuous flow membrane reactor.
Scheme 15: Enzymatic cyanohydrin formation in a microreactor.
Scheme 16: Resolution of (R/S)- 54 with immobilized lipase in a continuous scCO2- flow reactor.
Scheme 17: Enantioselective separation of Acetyl-D-Phe in a continuous flow reactor.